As I recall, at the time they met, she wanted sponsorship and introductions for her own films. So she was willing to go out with him. And probably he thought it would be interesting to have sex with a porn actress. Maybe he wondered whether it'd better than all the other sex he'd had.
As I also recall, she only went out with him twice. Once in 2006, and once again around 2010. The second time, they didn't go to bed; he just wanted to watch Shark Week.
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