When I informed myself years ago on the subject I remember heat doing the trick and conversation about capturing more to make the cell efficient. here is some information on solar cells. there is plenty out there, I only hope GTEM has it nailed down.
"A solar cell has silicon with impurities -- other atoms mixed in with the silicon atoms, changing the way things work a bit. We usually think of impurities as something undesirable, but in our case, our cell wouldn't work without them. These impurities are actually put there on purpose. Consider silicon with an atom of phosphorous here and there, maybe one for every million silicon atoms. Phosphorous has five electrons in its outer shell, not four. It still bonds with its silicon neighbor atoms, but in a sense, the phosphorous has one electron that doesn't have anyone to hold hands with. It doesn't form part of a bond, but there is a positive proton in the phosphorous nucleus holding it in place.
When energy is added to pure silicon, A solar cell has silicon with impurities -- other atoms mixed in with the silicon atoms, changing the way things work a bit. We usually think of impurities as something undesirable, but in our case, our cell wouldn't work without them. These impurities are actually put there on purpose. Consider silicon with an atom of phosphorous here and there, maybe one for every million silicon atoms. Phosphorous has five electrons in its outer shell, not four. It still bonds with its silicon neighbor atoms, but in a sense, the phosphorous has one electron that doesn't have anyone to hold hands with. It doesn't form part of a bond, but there is a positive proton in the phosphorous nucleus holding it in place.
When energy is added to pure silicon, for example in the form of heat, it can cause a few electrons to break free of their bonds and leave their atoms. A hole is left behind in each case. These electrons then wander randomly around the crystalline lattice looking for another hole to fall into. These electrons are called free carriers, and can carry electrical current. There are so few of them in pure silicon, however, that they aren't very useful. Our impure silicon with phosphorous atoms mixed in is a different story. It turns out that it takes a lot less energy to knock loose one of our "extra" phosphorous electrons because they aren't tied up in a bond -- their neighbors aren't holding them back. As a result, most of these electrons do break free, and we have a lot more free carriers than we would have in pure silicon. The process of adding impurities on purpose is called doping, and when doped with phosphorous, the resulting silicon is called N-type ("n" for negative) because of the prevalence of free electrons. N-type doped silicon is a much better conductor than pure silicon is.
Actually, only part of our solar cell is N-type. The other part is doped with boron, which has only three electrons in its outer shell instead of four, to become P-type silicon. Instead of having free electrons, P-type silicon ("p" for positive) has free holes. Holes really are just the absence of electrons, so they carry the opposite (positive) charge. They move around just like electrons do.
The interesting part starts when you put N-type silicon together with P-type silicon. Remember that every PV cell has at least one electric field. Without an electric field, the cell wouldn't work, and this field forms when the N-type and P-type silicon are in contact. Suddenly, the free electrons in the N side, which have been looking all over for holes to fall into, see all the free holes on the P side, and there's a mad rush to fill them in.
, it can cause a few electrons to break free of their bonds and leave their atoms. A hole is left behind in each case. These electrons then wander randomly around the crystalline lattice looking for another hole to fall into. These electrons are called free carriers, and can carry electrical current. There are so few of them in pure silicon, however, that they aren't very useful. Our impure silicon with phosphorous atoms mixed in is a different story. It turns out that it takes a lot less energy to knock loose one of our "extra" phosphorous electrons because they aren't tied up in a bond -- their neighbors aren't holding them back. As a result, most of these electrons do break free, and we have a lot more free carriers than we would have in pure silicon. The process of adding impurities on purpose is called doping, and when doped with phosphorous, the resulting silicon is called N-type ("n" for negative) because of the prevalence of free electrons. N-type doped silicon is a much better conductor than pure silicon is.
Actually, only part of our solar cell is N-type. The other part is doped with boron, which has only three electrons in its outer shell instead of four, to become P-type silicon. Instead of having free electrons, P-type silicon ("p" for positive) has free holes. Holes really are just the absence of electrons, so they carry the opposite (positive) charge. They move around just like electrons do.
The interesting part starts when you put N-type silicon together with P-type silicon. Remember that every PV cell has at least one electric field. Without an electric field, the cell wouldn't work, and this field forms when the N-type and P-type silicon are in contact. Suddenly, the free electrons in the N side, which have been looking all over for holes to fall into, see all the free holes on the P side, and there's a mad rush to fill them in. "
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