Thursday, June 30, 2016 5:34:54 PM
"While there is vast potential in terms of applications of the technology, our initial focus will be on energy storage, solar, microelectronics, and printable electronics, as we seek to generate immediate revenue for the company and build long term partnerships with manufacturers."
From the NDSU Research Foundation website:
Energy Storage:
Electrospinning Process and Compositions for High Volume Silicon Nanowire Productions (RFT-311)
North Dakota State University (NDSU) has developed unique synthetic routes to a novel liquid silicon precursor, cyclohexasilane (Si6H12), which is converted to silicon nanowires by electrospinning. Readily purified by distillation, the liquid nature of Si6H12 allows the development of a high-volume electrospinning route for silicon nanowire production. Because the spun wires convert to amorphous silicon at relatively low temperatures, formation of excessive surface oxide and carbide phases can be avoided which would otherwise negatively affect capacity and rate capabilities. The technology can be used in the development of anodes for use in next-generation lithium ion batteries, in which the traditional carbon-based anode is replaced with a silicon-based anode for a dramatic increase in capacity (theoretically over 1100% increase in capacity).
Solar and Microelectronics:
Roll-to-Roll Synthesis of Silicon Thin Films from Liquid Silanes (RFT-447)
Silicon thin films are fundamental in solar and microelectronic industries, and are presently obtained using expensive low-pressure plasma enhanced chemical vapor deposition (PECVD) using gaseous silanes despite of its low precursor utilization efficiency. Instability and low vapor-pressure of liquid hydrosilanes have limited their use in the semiconductor industries for longtime. Researchers at NDSU have developed a process to synthesis silicon thin films from liquid hydrosilane (Si6H12) at ambient pressure in a roll-to-roll method using atmospheric pressure aerosol assisted chemical vapor deposition (AA-APCVD) that has higher deposition rates compared to the state-of-the-art PECVD. Solubility of solid dopants in the liquid hydrosilane facilitate the deposition of degenerately doped (n & p –type) Si thin films opposed to compressed toxic phosphine and borane gases used in other techniques. Low decomposition temperature (higher activation energy) of cyclohexasilane (Si6H12), a liquid hydrosilane, benefits for a new plasma-free process for the synthesis of silicon nitride films and Si nanowires (with suitable catalyst) at temperatures as low as 350 oC using the AA-APCVD, readily adoptable for large-scale roll-to-roll continuous manufacturing. Liquid hydrosilane compositions consisting of nanomaterials enable hybrid Si films with embedded nanomaterials that have applications in energy harvesting and light emitting devices.
www.ndsuresearchfoundation.org (click-on Technologies, Chemistry & Materials)
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