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oh yeah and ETMMs prolly some impatient retail with 2 or 3 million
only one with shares IMO is WECK, at least anything substantial. They are stacking it creating a false wall. I do beleive however WECKs shares are inthe 35 to 45 million area
last time it did this it was between the 0004 and 0006 range then we saw 12/18/24 respectively
Very Typical of this stock
They have alot to get rid of, gotta be patient and wait for the, well we will call them "big fish" to get rich first
I am not arguing that point but is the guy wants to hear it for himself from the horsesmouth, as I would, that is who he has to call
13367230908 if they try to give you Gerry Millers number at Orion Financial just say he doesnt have any current info on the ss, you prefer to talk with Joe Overcash to obtain the information about the share structure
You need to call Joe Overcash for the SS
doubt for long..
35m on the ask fellas
aww who doesnt LOVE a kid with a 8 dollar stock book?
he is the one who does the pinksheet updates, if you get him ask him to update the ss on pinksheets casue alot of people are wondering, he probably will do it. Dont let them push you off to Gerry Miller at Orion he knows nothing
thats Gunthers number, you need to speak with Gunther or Joe to get the info on the current SS
When the cats away the mouse will play! I think someone is being compensated between the sheets here unbeknowns to someone else! And the compensator is enjoying grazing on the other side of the fence! LMAO
Ngith all, see ya in the AM!
ayep sure was JLEO was there before that, this is the typical pattern of this stock IMO
WECK apparently seems to be the Market Maker of choice for the guys running the paid promos, not the company. The potential exists for the stock price to increase significantly in the next few days imo. Are they done selling? Who knows, my guess is more than likely they are for a little bit, we will see them again however.
You all need to jsut get a good nigth rest and be ready to go to the bar tomorrow night!
I actually dont doubt you MasterT, I tend to assume the same thing
Maybe thats where Billy Strange is entering the numbers! lol, "Pressing the Button!"
Its kinda sorta jsut a figure of speach JuJu, Im not reading anything, eventually you will get accostumed to my "sense of humpr" GLTY
That is the problem ERhino, agree totally these "Promo guys" are currently accomplishing nothing but raising suspicion with the not so seasoned investors
Where you guys think half these posters are from?
hundreds of millinos of shares to paid promo guys go figure
you mean a promoter?
Panhandle Oil and Gas Inc. (Panhandle) is engaged in the acquisition, management and development of oil and gas properties, including wells located on the Company’s mineral acreage. Panhandle’s mineral properties and other oil and gas interests are located primarily in Arkansas, Kansas, Oklahoma, New Mexico and Texas. Approximately 80% of oil and gas revenues are derived from the sale of natural gas. Substantially all the Company’s oil and gas production is sold through the operators of the wells. NYSE: PHX Recent Price: $21.20
· Daybreak Oil and Gas, Inc. (Daybreak) is an exploration-stage oil and natural gas exploration, development and production company. The Company’s operations are focused on identifying and evaluating prospective oil and gas properties, and funding projects. The Company has onshore oil and gas projects in California, Alabama and Louisiana. The Company owns mineral property interests (which it has explored for commercial mineral deposits) on public and private lands in various states in the United States. OTCBB: DBRM Recent Price:$.13
these guys being compared to PMDP lol no fn way
Oh BTW something else i never shared, that Tony Katz guy, hes from OTC Reporter, Overcash pushed me off to him, the guy is a complete and total dickhead
Company Overview
Plateau Mineral Development, Inc. (OTC.PK: PMDP)
Plateau Mineral Development, Inc. specializes in the exploration and development of energy sources. Its partner, Plateau Mineral Development LLC, has been in existence for over five years with successful new wells and rework wells selling both gas and oil.
um yeah ok, this is going to get really fun
Leadership
Robert Matthews, CEO
Dominic Martinez, Secretary
Bill Strange, President
Glad to see I made ya laugh at least Curly =)
Seriously answered, if you are buying at these levels and hoping to wait till it hits 02 to sell you need to reconsider. The possibility of it hitting 02 exists but I would never hold my entire share count in the assumption of a gain of that magnitude....UNLESS of course you know some real solid information!
Better than a single woman over 35 getting married, course she also has a better chance of dying in a terrorist attack...
Im always on my side first, hey at least I'm honest. Either way Curly I will emerge a winner in this game here. Whether those winnings consist of a monitary value or just pure satisfaction, I will win, because I NEVER give up. Truely hope everyone here wins in some way. Maybe I will understand more as I read my book!
Look all the interest in buying carbon black! I wonder what grade(s) we are looking to make?
http://www.alibaba.com/buyeroffers/Carbon_Black.html
Just passing along info, that isnt anything that i know ALL of that is easily searchable on the internet! Look at the potential!
Who said I was?
In the meantime if you are bored here is something to read
The present invention relates to a new process for producing furnace carbon blacks and a class of new and novel furnace carbon blacks which are suitable for various applications and particularly well suited for use in rubber or plastic compositions.
BACKGROUND
Carbon blacks are generally produced in a furnace-type reactor by pyrolyzing a hydrocarbon feedstock with hot combustion gases to produce combustion products containing particulate carbon black. A variety of methods for producing carbon blacks are generally known.
In one type of a furnace carbon black reactor, such as shown in U.S. Pat. No. 3,401,020 to Kester et al., or U.S. Pat. No. 2,785,964 to Pollock, hereinafter "Kester" and "Pollock" respectively, a fuel, preferably hydrocarbonaceous, and an oxidant, preferably air, are injected into a first zone and react to form hot combustion gases. A hydrocarbon feedstock in either gaseous, vapor or liquid form is also injected into the first zone whereupon pyrolysis of the hydrocarbon feedstock commences. In this instance, pyrolysis refers to the thermal decomposition of a hydrocarbon. The resulting combustion gas mixture, in which pyrolysis is occurring, then passes into a reaction zone where completion of the carbon black forming reactions occurs.
In another type of furnace black reactor, a liquid or gaseous fuel is reacted with an oxidant, preferably air, in the first zone to form hot combustion gases. These hot combustion gases pass from the first zone, downstream though the reactor, into a reaction zone and beyond. To produce carbon black, a hydrocarbonaceous feedstock is injected at one or more points into the path of the hot combustion gas stream. The hydrocarbonaceous feedstock may be liquid, gas or vapor, and may be the same or different from the fuel utilized to form the combustion gas stream. Generally the hydrocarbonaceous feedstock is a hydrocarbon oil or natural gas. However, other hydrocarbonaceous feedstocks such as acetylene are known in the art. The first (or combustion) zone and the reaction zone may be divided by a choke, or zone of restricted diameter, which is smaller in cross section than the combustion zone or the reaction zone. The feedstock may be injected into the path of the hot combustion gases upstream of, downstream of, and/or in the restricted diameter zone. Furnace carbon black reactors of this type are generally described in U.S. Pat. Reissue No. 28,974 and U.S. Pat. No. 3,922,355.
In both types of processes and reactors described above, and in other generally known reactors and processes, the hot combustion gases are at a temperature sufficient to effect pyrolysis of the hydrocarbonaceous feedstock injected into the combustion gas stream. In one type of reactor, such as disclosed in Kester, feedstock is injected, at one or more points, into the same zone where combustion gases are being formed. In other type reactors or processes the injection of the feedstock occurs, at one or more points, after the combustion gas stream has been formed.
In either type of reactor, following the point of feedstock introduction, the feedstock is mixed, atomized and vaporized into the combustion gas stream. The mixture of combustion gases and vaporized feedstock then enters the primary reaction zone. The term, "primary reaction zone", refers to that zone in the process where the vaporized hydrocarbon feedstock is converted to carbon black primary particles and aggregates. The residence time of the feedstock, combustion gases, and carbon blacks in the primary reaction zone of the reactor is sufficient, and under conditions suitable, to allow the formation of carbon blacks. A secondary reaction zone may or may not exist in the reactor downstream of the primary reaction zone. In those cases where the secondary reaction zone exists, the term "secondary reaction zone" refers to that portion of the reactor where surface modification of the carbon blacks formed in the primary reaction zone takes place. The mixture of combustion gases and carbon blacks in the secondary reaction zone of the reactor is hereinafter referred to, throughout the application, as "the effluent". After carbon blacks having the desired properties are formed, the temperature of the effluent is lowered to stop the major reactions. This lowering of temperature of the effluent to stop the major reactions may be accomplished by any known manner, such as by injecting a quenching fluid, through a quench, into the effluent. As is generally known to those of ordinary skill in the art, the major reactions are stopped when the desired carbon blacks have been produced in the reactor, as is determined by sampling the carbon black and testing for analytical properties. After the reactions have been stopped and the effluent sufficiently cooled by any known means, the effluent generally passes through a bag filter, or other separation system to collect the carbon black.
Although two general types of furnace carbon black reactors and processes have been described, it should be understood that the present invention can be used in any other furnace carbon black reactor or process in which carbon black is produced by pyrolysis and/or incomplete combustion of hydrocarbons. This process differs from prior technology in that an oxidant-containing stream is introduced into the secondary reaction zone in order to accelerate and promote surface modifying reactions in the secondary reaction zone only. Throughout this application, the term "oxidant-containing stream" refers to any stream which contains an oxidizing agent. Preferably, `oxidant-containing stream` refers to air, oxygen-enriched air, combustion products of hydrocarbon fuels and air and/or oxygen, or mixtures of these streams. This oxidant-containing stream does not interfere with reactions or processes occurring in the primary reaction zone in which the carbon black primary particles and aggregates are formed.
In the prior art, there are references such as U.S. Pat. Nos. 3,607,058; 3,761,577; and 3,887,690 which describe the introduction of secondary heat into a carbon black reactor. These references differ from the present invention in that a minimum residence time, determined by the temperature increase of the effluent after addition of an oxidant-containing stream to the secondary reaction zone, is required to achieve the benefits of the present invention. No residence time or minimum temperature rise after addition of secondary heat is specified in the prior art references. From the examples cited in U.S. Pat. No. 3,887,690, the analytical properties of the carbon blacks, particularly the fact that the Nitrogen Surface Area is greater than the Iodine Adsorption Number in all cases, indicate that the minimum residence time requirement of the present invention has not been achieved.
Carbon blacks may be utilized as pigments, fillers, reinforcing agents and for a variety of other applications. Carbon blacks are widely utilized as fillers and reinforcing pigments in the compounding and preparation of rubber compositions and plastic compositions. Carbon blacks are generally characterized on the basis of their properties including, but not limited to, their surface areas, surface chemistry, aggregate sizes and particle sizes. The properties of carbon blacks are analytically determined by tests known to the art, including iodine adsorption surface area (I 2 No), nitrogen adsorption surface area (N 2 SA), dibutyl phthalate adsorption (DBP), dibutyl phthalate adsorption of the crushed carbon black (CDBP), cetyl-trimethyl ammonium bromide absorption value (CTAB), Tint value (TINT), Dmode and ?D50.
It is generally understood that the properties of a carbon black affect the properties of rubber or plastic compositions containing the carbon black. For example, the introduction of carbon black into a rubber or plastic composition during formation of the composition will generally affect the viscosity of the rubber or plastic composition. Increasing the carbon black loading in a rubber or plastic composition normally increases the viscosity of the composition at a given temperature. Lower viscosity rubber or plastic compositions are advantageous because they are more easily processed.
In addition to a variety of other uses, such as tire, hoses, belts, and plastics, carbon blacks are generally utilized in compositions intended for use as semi-conductive shielding compounds for electric power cables. Electric power cables generally consist of electrically conductive wires surrounded by a dielectric insulating material which prevents escape of electricity to the environment. These semi-conductive shielding compounds are critical for long cable life because they reduce the electrical stress between the conductive and insulating portions of the cable. It is generally desirable in the production of semi-conductive shielding compounds for electrical power cables to use carbon blacks which impart electrical conductivity to the shielding compound. In evaluating the conductivity of a plastic composition, the composition's resistivity is generally measured. However, it is widely understood that conductivity is simply the inverse of resistivity. The required degree of conductivity in the shielding compound can be achieved by increasing the loading of carbon black in the composition, but this also increases the compound viscosity. Therefore, it is apparent that it is advantageous to use a carbon black that imparts the required degree of conductivity while minimizing the compound viscosity. The advantage of optimizing this combination of properties is not limited to semi-conductive shielding materials for power cables.
The ASTM 300% modulus of a rubber compound is a measure of the compound's stress-strain relationship. ASTM Test D3192 describes the evaluation of modulus for a rubber compound. Carbon black specifications are often set based on the ability of the carbon black to impart a range of modulus values to a compound within certain narrow tolerances. It is advantageous to have a process that enables the carbon black producer to manipulate a composition's modulus for a given type of carbon black. Additionally, for certain applications, such as off-the-road automobile tires, a carbon black that imparts low modulus to rubber compounds is considered advantageous.
The Compound Moisture Absorption (CMA) property of a rubber or plastic composition relates to the composition's tendency to absorb moisture. It is generally desirable, for most applications, to have rubber or plastic compositions that do not absorb moisture. Therefore, it is advantageous to have a carbon black that, when incorporated into rubber or plastic compositions, results in a lower CMA for the composition. Lower CMA values are generally understood to relate to lower absorption of moisture.
As will be understood from the foregoing discussion, it would be advantageous to have a process for producing carbon blacks that impart improved conductivity to plastic or rubber compositions. It would be further advantageous to have class of carbon blacks that impart improved conductivity and lower viscosity to plastic or rubber compositions.
It would also be advantageous to have a process for producing carbon blacks that impart lower modulus to rubber compositions, lower CMA to plastic or rubber compositions and lower viscosity to plastic or rubber compositions.
The process of the present invention achieves the afore-mentioned advantages in addition to other advantages that will become apparent to those of ordinary skill in the art from the following description. Similarly the carbon blacks of the present invention achieve the afore-mentioned advantages and other advantages that will become apparent from the following description.
SUMMARY OF THE INVENTION
We have discovered a process for producing carbon blacks both of a conventional type and others which are novel as described hereinafter, wherein an oxidant-containing stream such as air, oxygen-enriched air, or combustion products of hydrocarbon fuel and air is injected into the reactor in the secondary reaction zone at a point after the primary-reaction zone in order to accelerate the rate of surface modifying reactions in the secondary reaction zone by raising the temperature in the secondary reaction zone without interfering with reactions which normally occur in the primary reaction zone.
The process is suitable for use in any carbon black reactor wherein the temperature of the effluent stream prior to the downstream oxidant-containing stream injection is greater than 1800° F. and less than 2700° F. The location of the downstream oxidant-containing stream injection is at any point downstream of the primary reaction zone and upstream of the quench which terminates reactions in the effluent. The amount of oxidant stream addition is sufficient to raise the reactor effluent temperature by a minimum amount, ?T min , depending on residence time, t, after oxidant addition and before quenching, defined by ?T min =1598° F.-6.20×(t,ms)
where ?T min =110° F.
and t=180 ms.
We have also discovered a new class of carbon blacks having an iodine adsorption number (I 2 No) of 35 mg/g (milligrams per gram) to 65 mg/g; a CTAB of 30 m 2 /g to 55 m 2 /g; and I 2 No/CTAB ratio of at least 1.12 mg/m 2 , preferably between 1.12 and 2.20 mg/m 2 , and more preferably between 1.12 and 1.50 mg/m 2 ; a CDBP (crushed dibutyl phthalate absorption) of 75 cc/100 g (cubic centimeters dibutyl phthalate per 100 grams carbon black) to 95 cc/100 g; a tint value (TINT), in %, of not greater than 65%, preferably between 30% and 65%. We have further discovered rubber and plastic compositions in which these carbon blacks are incorporated.
The carbon blacks of the present invention may be produced according to the process of the present invention in a furnace carbon black reactor having a first (combustion) zone, a feedstock injection zone, and a reaction zone consisting of a primary reaction zone and a secondary reaction zone. In the feedstock injection zone, a carbon black yielding feedstock is injected in any manner known to the art, into a hot combustion gas stream. The resultant mixture of hot combustion gases and feedstock passes first into the primary reaction zone and then into the secondary reaction zone. Reaction is stopped by quenching the mixture when the carbon blacks of the present invention have been formed. Preferably reaction is stopped by a quench injecting a quenching fluid. The process for preparing the novel carbon blacks of the present invention will be described in greater detail hereinafter.
The rubbers for which the novel carbon blacks of this invention are effective as reinforcing agents include any natural and synthetic rubbers. Generally, amounts of the carbon black product ranging from about 10 to about 250 parts by weight can be used for each 100 parts by weight of rubber. It is, however, preferred to use amounts varying from about 20 to about 100 parts by weight of carbon black per 100 parts by weight of rubber and especially preferred is the utilization of from about 40 to about 80 parts of carbon black per 100 parts of rubber.
Among the rubbers suitable for use with the present invention are natural rubber and its derivatives such as chlorinated rubber; copolymers of from about 10 to about 70 percent by weight of styrene and from about 90 to about 30 percent by weight of butadiene such as copolymer of 19 parts styrene and 81 parts butadiene, a copolymer of 30 parts styrene and 70 parts butadiene, a copolymer of 43 parts styrene and 57 parts butadiene and a copolymer of 50 parts styrene and 50 parts butadiene, polymers and copolymers of conjugated dienes such as polybutadiene, polyisoprene, polychloroprene, and the like, and copolymers of such conjugated dienes with an ethylenic group-containing monomer copolymerizable therewith such as styrene, methyl styrene, chlorostyrene, acrylonitrile, 2-vinyl-pyridine, 5-methyl-2vinylpyridine, 5-ethyl-2-vinylpyridine, 2-methyl-5-vinylpyridine, alkyl substituted acrylates, vinyl ketone, methyl isopropenyl ketone, methyl vinyl ether, alphamethylene carboxylic acids and the esters and amides thereof such as acrylic acid and dialkylacrylic acid amide; also suitable for use herein are copolymers of ethylene and other high alpha olefins such as propylene, butene-1 and pentene-1; particularly preferred are the ethylene-propylene copolymers wherein the ethylene content ranges from 20 to 90 percent by weight and also the ethylene-propylene polymers which additionally contain a third monomer such as dicyclopentadiene, 1, 4-hexadiene and methylene norbornene.
Any plastic is suitable for use with the present invention. Among the plastics suitable for use with the novel carbon blacks of this invention are polyethylene, including very low density, high density, and linear low density. Also included are copolymers such as ethylene ethyl acrylate, ethylene vinyl acetate, and ethylene butyl acrylate. Compositions made from blends of elastomers and plastics, both described above, are also suitable for use.
It is an advantage that the novel carbon blacks of the present invention impart, at a given resistivity, lower viscosity to plastic and rubber compositions than conventional comparable carbon blacks.
It is a further advantage that the process of the present invention produces carbon blacks which impart, at a given resistivity, lower viscosity to plastic and rubber compositions.
Another advantage is that the process of the present invention produces carbon blacks that impart lower modulus to rubber compositions at a given carbon black loading.
It is a further advantage that the process of the present invention may be utilized to produce carbon blacks that impart lower CMA (compound moisture adsorption) to rubber and plastic compositions.
It is an advantage that the plastic compositions of the present invention are particularly well suited for use as electric cable semi-conductive sheathing, with improved conductivity and processability characteristics.
Other advantages of the present invention will become apparent from the following more detailed description of the invention.
I really hope it does Curly, believe me I spend ALOT of time on this company.
08, but I guess we are making "solvent" not "oil"
The TR1500 is based on EWI’s RP process that reduces tires to carbon black, oil, steel and non-condensable gases. The Agreement will include specific performance requirements for TRD to retain exclusive rights in Israel and the designated European countries. This TR 1500 installation would be a showpiece for entering the European and Middle Eastern markets.
TRD reviewed several other processes presently being marketed as capable of extracting energy and reusable raw materials from organic items, like tires and oil shale, but concluded that EWI offered the best proven technology. TRD has placed an initial deposit of $180,000 in trust to be released upon the signing of the Agreement. If TRD and EWI do not complete the Agreement 75% of the deposit will be returned to TRD with EWI retaining the remaining 25%, half as an investment in EWI common shares and half as compensation.
Of course we are still looking for the answer in 05 so! Guess we just need someone to do it!
Mountains of used tires mar the landscape or burn in clouds of fetid black smoke. Chemically crosslinked rubber is one of the most difficult materials to recycle, and crumb rubber has yet to find its golden market. All seems hopeless until we read the 12 papers in this collection that prove the technology is available for effective recycling and reuse of rubber. Topics include the development of crumb rubber from whole tires, quality performance factors for tire- derived materials, treated and untreated rubber powder, electromechanical and high-temperature sintering methods of tire recycling, rubber recycling by blending with plastics, ultrasonic and thermomchanical vulcanization, conversion of tires to oil and new markets for scrap tires and recycled rubber.
I mean that was patented in 99 so Plateau must have better 11 years later no?